Abstract

AbstractBiomimetic Bouligand architecture is constructed in the ceramic to improve its toughness. Firstly, unidirectional carbon fiber‐reinforced ZrB2‐SiC ceramic films are achieved through a vacuum‐assisted filtration method using graphene oxide. Then, ceramic films are helically assembled at a fixed angle of 30° in the graphite die based on the fiber orientation. Finally, the spark plasma sintering method was utilized to densify helical assembly carbon fiber/ceramic films. By constructing Bouligand structure, high fracture toughness (7.4 MPa·m0.5) and work of fracture (∼1055 J/m2) are achieved in ZrB2‐based ceramic. The toughening mechanisms mainly are crack deflection, twisting and branching, carbon fiber pulling out, and bridging.

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