Mechanical evaluation of propylene polymers under static and dynamic loading conditions

Abstract

The present investigation is concerned with the evaluation of the impact toughness of commercial-grade Propylene polymers. Conventional impact static stress–strain and static fracture experiments were carried out. Static stress–strain experiments revealed different pattern behaviors among the materials that were reflected in the fracture behavior. Under static conditions, all materials exhibited ductile behavior and crack grew under J-controlled conditions displaying stress whitening through the whole fracture surface with the sole exception of the homopolymer, which displayed a ductile instability after some stable crack growth. Under dynamic conditions the homopolymer exhibited brittle behavior, the block copolymer exhibited some plastic deformation at the crack tip, and the random copolymer samples exhibited a whitening effect due to voiding and craze formation through the whole fracture surface, indicating that stable crack propagation was occurring. Fracture mechanics tests were analyzed by following different methods, depending on the mode of fracture presented by the polymer. The Normalization J-method was used under static conditions. The elastic method, the corrected elastic method, and the essential work of fracture methodology were used to characterize brittle, semibrittle, and ductile behavior, respectively. Fracture mechanics parameters arisen from both static and dynamic conditions are compared. © 1999 John Wiley & Sons, Inc. J Appl Polym Sci 74: 2681–2693, 1999