Mechanical and physicochemical properties of electron beam irradiated rubber/clay nanocomposites

Abstract

Effect of electron beam irradiation on the mechanical and physicochemical properties of both styrene butadiene rubber (SBR)/clay and ethylene propylene diene monomer (EPDM)/clay nanocomposites containing clay contents from 3 to 10 phr prepared by melt blending method has been investigated. The prepared composites were subjected to electron beam irradiation doses of up to 150 kGy to induce radiation curing, whereas the mechanical properties in terms of tensile strength (TS), tear strength (Ts), and elongation at break (Eb) were studied as a function of irradiation dose and clay content. TS and Ts increased with increasing irradiation dose up to 100 kGy, they were decreased with further increase in dose. An increase in TS and Ts for SBR and EPDM nanocomposites containing various organomodified montmorillonite (OMMT) contents (3–5 phr) was noticed, whereas a decrement behavior was observed at higher OMMT content. The elongation at break decreased continuously with both irradiation dose and OMMT content. The crosslink density for either EPDM or SBR samples increases with increasing irradiation dose up to 150 kGy and by increasing clay content up to 5 phr, whereas it decreases at higher clay content (7–10 phr). At 5 phr OMMT and 100 kGy irradiation, SBR nanocomposites showed higher TS and Ts than EPDM nanocomposites, while the crosslink density of SBR is lower. POLYM. COMPOS., 34:1600–1610, 2013. © 2013 Society of Plastics Engineers