Abstract
The mechanical and dynamic mechanical properties of blends of poly(ethylene- co-acrylic acid) (PEA) and epoxidized natural rubber (ENR-50) have been studied after reactive blending in various proportions in a Brabender Plasticorder. The miscibility of the blends has been studied by using a computer simulation method and experimentally confirmed by dynamic mechanical analysis. The dynamic properties of the blends exhibit single glass transition temperature ( T g) values, thus conforming to the law of miscibility. A positive deviation from the Fox equation (theoretical T g) is a clear indication of miscibility via chemical interaction. A new β-transition peak in the blends appeared, and this is assumed to be due to the side-chain ester group vibration, confirming a chemical reaction between the in situ generated OH groups of the ENR and free COOH groups of the PEA. This leads to miscibility between the constituents forming the grafted structure, i.e. PEA- g-ENR. The mechanical properties exhibit a synergism above that calculated via the additivity rule. The chemical interactions have been further confirmed by swelling studies in a common solvent.
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