Abstract
Abstract. The specific surface area (SSA) of snow can be used as an objective measurement of grain size and is therefore a central variable to describe snow physical properties such as albedo. Snow SSA can now be easily measured in the field using optical methods based on infrared reflectance. However, existing optical methods have only been validated for dry snow. Here we test the possibility to use the DUFISSS instrument, based on the measurement of the 1310 nm reflectance of snow with an integrating sphere, to measure the SSA of wet snow. We perform cold room experiments where we measure the SSA of a wet snow sample, freeze it and measure it again, to quantify the difference in reflectance between frozen and wet snow. We study snow samples in the SSA range 12–37 m2 kg−1 and in the mass liquid water content (LWC) range 5–32%. We conclude that the SSA of wet snow can be obtained from the measurement of its 1310 nm reflectance using three simple steps. In most cases, the SSA thus obtained is less than 10 {%} different from the value that would have been obtained if the sample had been considered dry, so that the three simple steps constitute a minor correction. We also run two optical models to interpret the results, but no model reproduces correctly the water–ice distribution in wet snow, so that their predictions of wet snow reflectance are imperfect. The correction on the determination of wet snow SSA using the DUFISSS instrument gives an overall uncertainty better than 11%, even if the LWC is unknown. If SSA is expressed as a surface to volume ratio (e.g., in mm−1), the uncertainty is then 13% because of additional uncertainties in the determination of the volume of ice and water when the LWC is unknown.
Highlights
Snow is a porous medium made of air, ice, small amounts of impurities and occasionally liquid water
Assuming for the moment that this approximation is acceptable, we propose that to measure the specific surface area (SSA) of wet snow with DUFISSS, we just need to measure its 1310 nm reflectance, obtain an apparent value from the relationships of Gallet et al (2009), add 0.5 m2 kg−1 to that value, and multiply by the factor ψ, which can be calculated with the coated sphere structural approximation (Eq 8)
We show that DUFISSS can measure the SSA of wet snow with an uncertainty of 11 %
Summary
Snow is a porous medium made of air, ice, small amounts of impurities and occasionally liquid water. It is one of the most, or perhaps even the most reflective surface on earth so that its albedo is a key parameter to determine the planetary energy budget (Hall, 2004; Lemke et al, 2007). The albedo of snow is determined mostly by its impurity content and grain size, but the liquid water content (LWC) plays a role (Warren, 1982). When present in small amounts, water is located only at grain boundaries (Colbeck, 1973; Ketcham and Hobbs, 1969) and a slight decrease in albedo is observed (Wiscombe and Warren, 1980). Gallet et al.: Measuring the specific surface area of wet snow using 1310 nm reflectance
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