Abstract
AbstractWe present measurements of second virial coefficients of the chlorofluorocarbons R12 (CCl2F2), R22 (CHCIF2), R114 (CClF2—CClF2), R134a (CH2F—CF3), R142b (CH3—CClF2), R152a (CH3—CHF2) and of the binary mixtures R12/R22, R22/R114, R22/R142b, R22/R152a, and R134a/R152a in the temperature range from 296 K to 475 K. The data are combined with earlier measurements of the same systems at low temperatures (J. Chem. Thermodyn. 23, 281 (1991)) for a critical discussion on the basis of the Stockmayer intermolecular potential model.
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