Abstract
The double-ionization energies of the eight chlorofluoroethane molecules have been measured by double-charge-transfer spectrometry. Several peaks were observed in most of the spectra giving information about the energies required to populate electronically excited states (or groups of states) of the dications as well as those to the ground states. In addition to the experimental study, the vertical double-ionization energies to the lowest triplet levels of the dications were calculated. In general, the calculated values are lower than those determined experimentally, but the addition of a uniform shift of 0.4 eV to them brings all calculated data to within ±0.7 eV of those measured. This agreement is quite good since the uncertainty associated with the measured double-ionization energies to the ground states is ±0.5 eV.
Published Version
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