Abstract
A mathematical model of polymer adsorption from solution onto a planar surface is suggested. The kinetic model takes into account the adsorption and desorption rates as well as the rates of bond formation and dissociation between the macromolecule and the surface. The correspondence of this kinetic model to experimental data for polystyrene adsorption onto a chromium surface from cyclohexane and replacement adsorption of protic polystyrene by deutero-polystyrene is shown. Some values of the rate constant ratios are found.
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