Abstract

We report that eight cadmium arenethiolate compounds with general formula ∞ n [Cd(SAr) 2 ] and cadmium phenylmethanethiolate ∞ n [Cd(SB) 2 ] (B 2 =CH 6 CH 5 ), when subjected to plasma desorption time-of-flight mass spectrometry, yield positive and negative ions up to 3.7 kDa. The spectra reveal extended series of ions containing both RS- and S 2-

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