Abstract
Mn(C6HllO7) 2. 2H20, 2C6HllO 7.Mn2+. - 2H20, triclinic, P1, a = 7.205 (5), b = 8.184 (4), c = 11.157 (6) A, ,t = 90.96(4), fl = 94.40(5), y = 137.34 (4) °, M r = 481.3, V = 441.9 (5)/~3, Z = 1, D m = 1.79, D x = 1.81 Mg m -a,/t(Cu Kct, 2 = 1.5418 A) = 7.24 mm -~, final R = 0.033 and R w = 0-045. The Mn atom is octahedrally coordinated by one carboxyl- ate O atom and one hydroxyl O atom from both gluconate ligands and two water O atoms in cis positions. Mn--O distances range between 2.091 (5) and 2.275 (5) /~. The independent gluconate ions assume different bent-chain conformations and one is bonded to two adjacent Mn atoms forming polymeric chains parallel to b. There is extensive intermolecular hydrogen bonding (and one intramolecular hydrogen bond) involving all the hydroxyl and water H atoms and holding the polymeric units together.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
