Magneto-optical properties and exciton dynamics in diluted magnetic semiconductor nanostructures

Abstract

Nanostructures of diluted magnetic semiconductors were fabricated to study novel magneto-optical properties that are derived from quantum confined band electrons interacting with magnetic ions. Quantum dots (QDs) of Cd 0.97Mn 0.03Se were grown by the self-organization on a ZnSe substrate layer. QDs of Zn 0.69Cd 0.23Mn 0.08Se and quantum wires (QWRs) of Cd 0.92Mn 0.08Se and Zn 0.69Cd 0.23Mn 0.08Se were fabricated by the electron beam lithography. A single quantum well (QW) of ZnTe/Zn 0.97Mn 0.03Te and double QWs of Cd 0.95Mn 0.05Te–CdTe were grown by molecular beam epitaxy. Magneto-optical properties and the formation and relaxation dynamics of excitons were investigated by ultrafast time-resolved photoluminescence (PL) spectroscopy. Excitons in these nanostructures were affected by the low-dimensional confinement effects and the interaction with magnetic ion spins. The exciton luminescence of the Cd 0.97Mn 0.03Se QDs shows the confined exciton energy due to the dot size of 4–6 nm and also shows marked increase of the exciton lifetime with increasing the magnetic field. The QDs of Zn 0.69Cd 0.23Mn 0.08Se fabricated by the electron beam lithography display narrow exciton PL spectrum due to the uniform shape of the dots. The exciton luminescence from the QWRs of Cd 0.92Mn 0.08Se and Zn 0.69Cd 0.23Mn 0.08Se shows the influence of the one-dimensional confinement effect for the exciton energy and the luminescence is linearly polarized parallel to the wire direction. The transient PL from the ZnTe/Zn 0.97Mn 0.03Te QWs displays, by the magnetic field, the level crossing of the exciton spin states of the nonmagnetic and magnetic layers and the spatial spin separation for the excitons. Cd 0.95Mn 0.05Te–CdTe double QWs show the injection of the spin polarized excitons from the magnetic well to the nonmagnetic QW.