Abstract

Heat capacity, resistivity and magnetic susceptibility data have been used to study electronic and magnetic properties of REBa2Cu3O7−x compounds. Neutron diffraction on the Ho compound shows identical crystal structure to YBa2Cu3O6.8. All the compounds are superconducting at Tc=(93±2) K. Magnetic transitions are observed in the heat capacity data at Tm=2.2, 0.95, 0.17, and 0.59 K for RE=Gd, Dy, Ho, and Er, respectively, and the magnetically ordered state is found to coexist with superconductivity. Estimates have been obtained for the magnetic moment in the crystal field ground state and the energy splitting of the first excited state crystal field level.

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