Abstract
In this work, magnetic molecularly imprinted polymers (MIPs) for specific recognition of Hydroxytyrosol (HT) were designed by vinyl-modified magnetic particles (Fe3O4@SiO2@VTEOs) as carrier, ternary deep eutectic solvent (DES) as functional monomer, while ethylene glycol dimethacrylate (EGDMA) as crosslinker. The optimum amount of DES was obtained by adsorption experiments (molar ratio, caffeic acid: choline chloride: formic acid=1:6:3) which were 140μL in total. Under the optimized amount of DES, the maximum adsorption capacity of the MIPs particles was 42.43mgg-1, which was superior to non-imprinted polymer (4.64mgg-1) and the imprinting factor (IF) is 9.10. Syringin and Oleuropicrin were used as two reference molecules to test the selectivity of the DES-MIPs particles. The adsorption capacity of HT was 40.11mgg-1. Three repeated experiments show that the polymer has high stability and repeatability (RSD=5.50).
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