Magnetic hydrophobic solids prepared from Pickering emulsions for the extraction of polycyclic aromatic hydrocarbons from chamomile tea

Abstract

Two types of magnetic hydrophobic solids were prepared by Pickering emulsion photopolymerization using polystyrene-modified magnetic nanoparticles (PS-MNPs) as emulsion stabilizers. Additionally, PS-MNPs provided magnetic character to the final solids. W/O Pickering emulsions were produced with high amounts of oily phase (above 50 wt%), while O/W Pickering emulsions were formed with higher amounts of aqueous phase (above 60 wt%). These two types of emulsions led to two kind of solids with very different structures despite being formed by the same components. In this way, W/O Pickering emulsions produced monolithic solids, while O/W Pickering emulsions formed magnetic microparticles. Multi-walled carbon nanotubes (MWCNTs) were also added to the emulsions to provide higher hydrophobic character to the final solids. The structure and morphology of both magnetic solids containing the MWCNTs was characterized by scanning electron microscopy (SEM). Finally, their extraction efficiency was evaluated using polycyclic aromatic hydrocarbons (PAHs) as target analytes, both qualitatively (visually by the fluorescence emitted before and after the extraction) and quantitatively (using gas chromatography coupled to mass spectrometry). Therefore, the LODs ranged from 1 to 4 μg L−1 and the LOQs were between 3 and 12 μg L−1. The reproducibility of the extraction procedure with different batches of emulsions was acceptable with RSD values <13%. Finally, a recovery study was carried out in complex matrices such as chamomile tea, obtaining excellent recovery values which ranged from 99 to 108%.