Abstract

In order to clarify magnetic properties of filled skutterudites, we analyze the Anderson model including seven f orbitals hybridized with an au conduction band using a numerical technique. For n=2 corresponding to Pr-based filled skutterudites, where n is the local f-electron number, even if the ground state is a singlet, there remain significant magnetic fluctuations from a triplet state with a small excitation energy. This result can be understood by the fact that f-electron states are clearly distinguished as itinerant and localized ones in the filled skutterudite structure. This picture also explains the complex results for f-electron magnetic susceptibility and entropy for n=1-13.

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