Abstract
The spin-orbit structure ofF A centres in KCl:Li and KCl:Na have been studied by means of the magnetic circular dichroism. Due to theirC 4V symmetry theF A centres have two different spin-orbit parameters, Δ‖ and Δ⊥, which only in the KCl:Li case follow the relation: Δ‖ < ΔF < Δ⊥ as expected from the theory. For a close comparison we have also reported our measurement of the spin-orbit coupling ofF centre in KCl. The spin-orbit parameters of theF andF A centres have been determined using the method of moment.
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