Abstract

ABSTRACT Machine learning techniques such as local binary pattern algorithm and convolutional neural network were applied to study textures of liquid crystal compound (S)-4’-(1-methyloctyloxycarbonyl) biphenyl-4-yl 4-[7-(2,2,3,3,4,4,4-heptafluorobutoxy) heptyl-1-oxy]-benzoate (3F7HPhH7). This compound exhibits in its polymorphism several smectic phases (smectic A, ferroelectric smectic C and antiferroelectric smectic C) and two glass states of antiferroelectric smectic C phase, which textures are difficult to distinguish. Proof-of-concept evidence is provided, demonstrating the ability of machine learning algorithms to identify transition temperatures and the respective phases involved. The article describes the procedure for preparing a dataset of textures obtained from polarised microscopy for classification using convolutional neural networks, especially in cases where the image dataset is unbalanced. It utilises the feature of their self-similarity and image augmentation, particularly the cropping procedure. A Kolmogorov–Smirnov test was conducted to check if selected images do not carry the same information.

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