Abstract
A series of Y2MoO6:0.01Er3+/0.09 Yb3+ upconversion phosphors doped with different concentrations of Li + ions (0.05, 0.10, 0.15, 0.20, 0.25, and 0.30 mol) were prepared by the high temperature solid phase reaction method, and their physical phase structures and upconversion luminescence were analyzed. At the excitation wavelength of 980 nm, the addition of Li+ sharply increased the upconversion luminescence intensity. With the increase of Li+ ion content, the luminescence intensity first increases and then decreases. When the doping amount reaches 0.25 mol, the luminescence intensity reaches the maximum, and the sample emits green light in the two-photon process. Y2MoO6:0.01Er3+/0.09 Yb3+/0.25Li + exhibits excellent temperature sensing properties. Its absolute sensitivity Sa reaches up to 0.012 K-1, the relative sensitivity Sr is 0.017 K-1 and the measurement error δT is less than 0.3 K at room temperature. Its temperature sensing performance is far superior to similar materials. In addition, Judd-Ofelt theory calculations revealed that in comparison with Y2MoO6:0.01Er3+/0.09 Yb3+, its Ω2 increased from 0.56 × 10−20 cm2 to 3.68 × 10−20 cm2, and the spectroscopic quality factor Ω4/Ω6 ratio reached 4.09, which is much higher than that of the other fluorescent materials. The main reason is that Li + replaces the Y3+ ion lattice site, causing lattice distortion and reducing the lattice symmetry around the active ion. The increase in asymmetry increases the possibility of spontaneous radiative transitions. It is shown that the prepared upconversion luminescent materials have potential applications in the field of solid-state lasers and optical sensing.
Published Version
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