Abstract
AbstractIn this paper, Y4GeO8:Bi3+,Eu3+ phosphor with dual emission centers was elaborated via conventional solid‐state reaction technology. Thorough research on the structure, morphology, and luminous properties of Y4GeO8:Bi3+,Eu3+ phosphor, the potential applications in optical thermometry were investigated by means of fluorescence intensity ratio and thermochromic techniques. Under 290 and 347 nm excitation, Y4GeO8:Bi3+,Eu3+ phosphor presents broadband emission from 3P1 → 1S0 transition of Bi3+ ions and characteristic emission peaks from 4f–4f transition of Eu3+ ions. Outstanding temperature‐sensing capabilities are acquired from Y4GeO8:Bi3+,Eu3+ phosphor. The maximum relative sensitivity (Sr) can attain 1.51% K−1 (λex = 290 nm). With temperature raising (303–513 K), the emitted color of Y4GeO8:Bi3+,Eu3+ phosphor (λex = 290 nm) shifts from faint yellow to red with a high chromaticity shift (0.180), which can be distinguished by the unaided eye clearly. Our results indicate that Y4GeO8:Bi3+,Eu3+ phosphor has potential applications in optical temperature measurement and high‐temperature safety marker.
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