Abstract

Semi-transparent perovskite solar cells are highly attractive for a wide range of applications, such as bifacial and tandem solar cells; however, the power conversion efficiency of semi-transparent devices still lags behind due to missing suitable transparent rear electrode or deposition process. Here we report a low-temperature process for efficient semi-transparent planar perovskite solar cells. A hybrid thermal evaporation–spin coating technique is developed to allow the introduction of PCBM in regular device configuration, which facilitates the growth of high-quality absorber, resulting in hysteresis-free devices. We employ high-mobility hydrogenated indium oxide as transparent rear electrode by room-temperature radio-frequency magnetron sputtering, yielding a semi-transparent solar cell with steady-state efficiency of 14.2% along with 72% average transmittance in the near-infrared region. With such semi-transparent devices, we show a substantial power enhancement when operating as bifacial solar cell, and in combination with low-bandgap copper indium gallium diselenide we further demonstrate 20.5% efficiency in four-terminal tandem configuration.

Highlights

  • Semi-transparent perovskite solar cells are highly attractive for a wide range of applications, such as bifacial and tandem solar cells; the power conversion efficiency of semitransparent devices still lags behind due to missing suitable transparent rear electrode or deposition process

  • The bifacial cell concept has been implemented in various kinds of solar cell technologies[8,9,10,11,12], and up to 50% output power enhancement has been demonstrated in Si wafer bifacial modules by collecting the albedo radiation from surroundings[13]

  • The state-of-the-art perovskite solar cells[3,18,19,20,21,22] employ high-temperature-processed (B500 °C) TiO2 as electron transporting layer (ETL), which is incompatible with monolithic tandem or flexible solar cells on plastics

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Summary

Introduction

Semi-transparent perovskite solar cells are highly attractive for a wide range of applications, such as bifacial and tandem solar cells; the power conversion efficiency of semitransparent devices still lags behind due to missing suitable transparent rear electrode or deposition process. We employ high-mobility hydrogenated indium oxide as transparent rear electrode by room-temperature radio-frequency magnetron sputtering, yielding a semi-transparent solar cell with steady-state efficiency of 14.2% along with 72% average transmittance in the near-infrared region. With such semi-transparent devices, we show a substantial power enhancement when operating as bifacial solar cell, and in combination with low-bandgap copper indium gallium diselenide we further demonstrate 20.5% efficiency in four-terminal tandem configuration. High-mobility hydrogenated indium oxide (In2O3:H) is employed as transparent rear electrode through a room-temperature radio-frequency magnetron sputtering, which enables a semi-transparent device with steady-state efficiency of 14.2% and 72% average a PCBM ZnO FTO/glass b. Such a device when operated as a bifacial cell yields an additional 13.5% power output improvement, and 20.5% efficiency is demonstrated using perovskite top cell and CIGS bottom cell in four-terminal tandem configuration

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