Low viscosity & high-performance resorcinol epoxy acrylate preparation & application in stereolithography 3D printing

Abstract

Purpose There is a rising demand for high-performance 3D printed objects that have established potential applications in the sector of dental, automotive, electronics, aerospace, etc. Thus, to meet the requirements of high-performance 3D printed objects, this study has synthesized, formulated and applied a resorcinol epoxy acrylate (REA) oligomer to a stereolithography (SLA) 3D printer. Design/methodology/approach Different formulations were developed by blending reactive diluents in the concentration of 10%, 15% and 20%, along with the fixed quantity of photo-initiators in the REA oligomer. The structure of synthesized REA oligomer was confirmed using 13 C nuclear magnetic resonance (NMR) and 1H NMR spectroscopy, and the rheological properties for prepared REA formulations were also evaluated. The ultraviolet (UV)-cured specimens of all REA formulations were thoroughly examined based on physical, chemical, optical, mechanical and thermal properties. The best suitable formulation was selected for SLA 3D printing. Findings As perceived, UV cured REA specimens exhibit superior mechanical, chemical and thermal properties, portraying the ability to use as a high-performance material. The increase in the concentration of reactive diluents indicated a significant improvement in the properties of REA resin. The 20% diluted formulation achieved excellent compatibility with a SLA 3D printer; thus, 3D objects are cast with good dimensional stability and printability. Originality/value Resorcinol-based resins have always been a key additive used to enhance properties in the coating and tire industry. In a new attempt UV, curable REA has been applied to a SLA 3D printer to cast high-performance 3D printed objects.