Abstract
The optical properties of ZnO nanorods and nanowires grown by our newly developed nanoparticle-assisted pulsed-laser deposition (NAPLD) technique were studied by photoluminescence (PL) spectroscopy. This NAPLD technique, which does not require a catalyst for crystal growth, is expected to synthesize high-quality nanostructured ZnO crystals. The green luminescence (GL) band and ultraviolet luminescence (UVL) observed at low temperature were investigated for these crystals. The UVL band consists of several sharp emission lines due to free excitons, donor-bound excitons, donor-acceptor pair (DAP) transitions, and their longitudinal-optical (LO) phonon replicas. The free-exciton binding energy was estimated to be 59 meV and the band gap of these ZnO crystals was determined to be 3.435 eV at 10 K. The temperature variation for the energy positions of free-exciton emission was fitted by the Manoogian–Woolley equation and the Debye temperature was estimated to be 505 K. The low-temperature PL investigation of our nanostructured ZnO crystals that were easily synthesized by our newly developed NAPLD technique demonstrated their excellent crystallinity.
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