Abstract
The polarised luminescence spectrum of Ru(bpy) 3 2+ doped in single crystal Cd(bpy) 3(PF 6) 2 shows a smaller Stokes shift than that observed in the isomorphous Zn host, although absorption spectra are almost identical. Polarised, temperature dependent and time resolved luminescence spectra demonstrate the extent of non-thermalisation in the luminophore below 10 K.
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