Low-pressure ultraviolet-H2O2 photolysis for restoring the anodic stripping voltammetry signal: a new strategy for the detection of heavy metal ions in complex organic matter.

Abstract

A new strategy based on low-pressure ultraviolet (LPUV)-H2O2 advanced oxidation photolysis for the quantitative determination of organic heavy metal ions (HMIs) in soil was proposed for the efficient, low-cost, accurate, and green detection of Pb(II) and Cd(II) in soil extracts by breaking the complexation of HMIs and organic matters, consequently restoring the ASV signals of target HMIs. The key parameters of the proposed LPUV-H2O2 photolysis system for the restoration of stripping responses were optimized; the conversion of organic matter to inorganic matter during the photolysis was investigated by total organic carbon (TOC); the degradation kinetics of humic acid sodium (HAS) was measured by UV-vis spectroscopy (UV); the pathway of HAS converted to small molecule organics during degradation was observed by fluorescence spectroscopy (FS); additionally, Fourier transform infrared spectroscopy (FTIR) was used to study the complexation between HAS and HMIs. The results showed that the stripping signals of target HMIs in the simulated soil samples can be restored to nearly 100% with a good repeatability, and the restoration ratio of the stripping signal fluctuated within 10%. And the feasibility of the proposed method for the accurate detection of HMIs in the real soil samples was verified; the results showed that 93.7% of Cd(II) and 92.5% of Pb(II) in real soil extracts were detectable.