Abstract
In order to investigate the potential ionic liquid properties of Reineckate-analogue materials, four new salts, consisting of the heteroleptic [Cr(NCS)(4)(bipy)](-) complex anion and imidazolium-based cations A(+) = 1-ethyl-3-methylimidazolium, 1-n-butyl-3-methylimidazolium, pentamethylimidazolium, and 1,3-dimethyl-2,4,5-triphenylimidazolium, were investigated. Their structures were established by single-crystal X-ray diffraction. The compounds are paramagnetic with effective magnetic moments in the range of those expected by the number of unpaired spins of the chromium(III) ion. All melting points are above 100 °C, which prevents us from calling these compounds "ionic liquids". Nevertheless, they are low for salts of this constitution and may be useful for molten salt reactions. Cyclic voltammetry measurements show no reversible electron-transfer steps.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.