Abstract
Non-pumping reactive wells (NPRWs) are subsurface structures used for the passive treatment of contaminated groundwater using wells containing reactive media. In the vicinity of NPRWs, a combination of hydrogeological and chemical processes makes it difficult to predict their longevity. In this study, we evaluated the longevity of NPRWs using the upscaling methods. A horizontal two-dimensional sandbox was constructed to mimic the hydrogeological and chemical processes in a single unit of NPRW (unit NPRW). The groundwater flow and solute transport were simulated numerically to validate the processes of contaminant spreading prevention in the sandbox. Dye tracing and arsenic transport tests showed different performance of NPRW due to induced flow and uneven consumption of reactivity, which is dependent on the pathway length and residence time of the coal waste. Through numerical modeling of the experiments, the fate-related processes of contamination around NPRW were described in detail in both spatial and temporal terms. The stepwise approach of the upscaling methods was used to predict the contamination-blocking performance of the entire facility based on the reactivity of the materials and the contamination removal of the unit NPRW.
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