Abstract
A TiB2–TiCxN1−x quasi‐binary eutectic composite, with a rod‐like faceted texture and a long‐range ordered structure of Ti–B–C–N, was prepared by the arc‐melting of TiB2, TiC, and TiN powders. Hexagonal single‐crystalline TiCxN1−x rods were grown in a single‐crystalline TiB2 matrix with a crystal orientation relationship of TiB2 //TiCxN1−x and TiB2 [0001]//TiCxN1−x [111]. A long‐range ordered structure of Ti–B–C–N was formed by the intermixing of the coherent interplanar spacings of seven TiB2 (0001) and nine TiCxN1−x (111) planes.
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