Abstract

A guanine radical cation G induces electron transfer from a distal guanine Gb through DNA over long adenine:thymine (A:T)n bridges according to Equation (1). For n≤3, only guanine bases are charge carriers and the electron transfer rate kCT depends strongly upon the distance. For n≥4, not only guanines but also adenines are charge carriers and the charge transfer rate from Ga to Gb only slightly decreases with a further increase in n. This effect is shown in the graph. The yields of the water-trapped products are described by the Curtin–Hammett principle.

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.