Donor-length dependent photoninduced charge transfer in two-photon absorption.

Abstract

In this paper, we study the donor-length dependent photoinduced charge transfer in two-photon absorption (TPA). In the donor-acceptor (D-A) system of oligo-thiophene-fullerene, two kind of lengths of oligo-thiophene are chosen to study the donor-length dependent photoinduced charge transfer in TPA. It is found that donor length can significantly influence the rate of charge transfer. When the donor length is quarter-thiophene, the rate of charge transfer is less than 50%; while with the increase of donor-length to octant-thiophene, the rate of charge transfer can be reach up to 100%. The transition channels of photoinduced charge transfer in TPA are visualized with transition density matrix and charge difference density. Our results promote deeper understanding and rational design for donor-acceptor system with large rate of photoinduced charge transfer in TPA.