Lithofacies and petrochemical characterization of volcano-sedimentary sequence of Chandil Formation around Kharidih-Bareda area, Seraikela-Kharsawan District, Jharkhand: implications for uranium mineralization

Abstract

Mesoproterozoic Chandil Formation (ca. 1600 Ma) of North Singhbhum Mobile Belt record numerous features of felsic volcaniclastics and felsic to intermediate volcanics preserved in the central sector of the fold belt around Kharidih-Bareda area, Seraikela-Kharsawan district, Jharkhand. The felsic volcanic rocks exhibit flow bands, autoclasts and layering of crystal mushes revealing viscous nature of eruptives. The volcaniclastic sediments comprise of significant proportion of volcanic epiclasts and accidental lithic fragments. These volcaniclastics have been categorized into five prominent lithofacies viz, stratified lapilli tuff, banded tuff, tuff with penecontemporaneous deformation, welded lapilli stones, vitric tuff and volcanic bombs by field and petrographic studies of outcrops and subsurface borehole cores. The welded lapilli tuffs display fiamme and eutaxitic texture. Interlayering of the volcaniclastics, which are most often pyrite-rich, with psamo-pelitic lithology like carbonaceous phyllite, variegated phyllite, quartzite and minor limestone is suggestive of marine euxenic depositional environment. Petrographic study of the volcaniclastics indicated presence of glass shards, garnet phenocrysts, spherules of tremolite, ovoid to lenticular accretionary lapilli along with devitrified glassy material. Compositionally these felsic volcanics and volcaniclastics are rhyodacitic to andesitic in nature with peraluminous to meta aluminous in character. A/CNK values vary from 0.52 to 2.42 in felsic volcanics and from 0.12 to 1.63 in volcaniclastics. Signatures of arc magmatism is indicated by low concentration of HFS elements such as Nb (5-17 ppm), Ga (11-17 ppm) and Y (5-28 ppm). Elevated intrinsic content of uranium (3-8 ppm), Th/U ratio ranging from 1.2 to 13.2, presence of metamict allanite and zircon in volcanics and volcaniclastics reveal their suitability as a prospective source for search of uranium mineralization. The volcanic-volcaniclastic-clastic association of the Chandil Formation provides an ideal situation where provenance and province both are available. Thus, suitable litho-structural locales such as the concealed shear zones sympathetic to the Dalma thrust and South Purulia Shear Zone within the volcano-sedimentary package of Chandil Formation may be targeted as preferable sites for locating concealed uranium mineralization.