Abstract
The Conformal Solution and Flory's expressions for the free energy of mixing ΔGM of a binary liquid alloy have been modified by using a form for the enthalpy of mixing ΔHM which incorporates the concentration dependence given by Miedema's semiempirical model. This model emphasizes the importance of the atomic cell-surface area concentration in evaluating ΔHM. The modified forms of ΔGM have been used to construct the liquidus curves of NaCs and NaK.
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