Abstract
Cyclohexene and tetralin can be oxidized to a slight extent by N 2O in the presence of quaternary ammonium salt promoters under mild experimental conditions. In non-polar solutions, the higher yields of the oxidations of cyclohexene and tetralin are influenced by the donor–acceptor properties of the solvents. The changes in the IR spectrum of N 2O lend further support to the assumption that ion-pair interactions between the solvated oxidant and the onium salts result in an enhanced rate of O-transfer from the oxidant. Onium-decavanadate ion-pair complexes are more effective promoters than simple onium salts.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
