Liquid phase hydrodechlorination of chlorophenols at lower temperature on a novel Pd catalyst

Abstract

Pd catalyst supported on mesoporous silica–carbon nano-composite (Pd/MSCN) was prepared by the method of wet impregnation, and its activity for hydrodechlorination (HDC) of 2-chlorophenol, 4-chlorophenol and 2,4-dichlorophenol was evaluated at 258–313K under ordinary hydrogen pressure by using triethylamine (Et3N) as a base additive. XRD analysis indicates that Pd/MSCN catalyst possesses the ordered mesostructure. Meanwhile, the results from TEM and H2 chemisorption analysis indicate the high dispersion of Pd on MSCN with Pd nanoparticles whose average size is 3.2nm. For the first time, the high activity of nano-size Pd on MSCN for HDC of chlorophenols was observed at 258K. In addition, it was found that the inhibition effect of Et3N on HDC existed obviously, and can be efficiently reduced by stepwise addition of Et3N. The correlations of the dielectric constants of base and the polarity of solvent to the activity of Pd/MSCN for HDC of chlorophenols were obtained.