Liquid Phase Behavior of Imidazolium-Based Ionic Liquids with Alcohols

Abstract

Ionic liquids have been suggested as replacement solvents in reactions and separations since they have negligible vapor pressure; thus, they would reduce fugitive emissions that are common when organic solvents are used in these applications. To fully utilize ionic liquids in reactions and separations, a fundamental understanding of the factors that govern the phase behavior of ionic liquids with other common liquids is necessary. In this work, we present a systematic study of the impact of different factors on the phase behavior of imidazolium-based ionic liquids with alcohols. All systems examined showed upper critical solution temperature (UCST) behavior, with low solubility of the ionic liquid in the alcohol and high solubility of the alcohol in the ionic liquid. An increase in the alkyl chain length of the alcohol resulted in an increase in the UCST. Branching of the alcohol resulted in a higher solubility of the alcohol in the ionic-liquid-rich phase. By increasing the alkyl chain length on the cati...