Abstract
ABSTRACTLithium ions were extracted from aqueous solutions into cyclohexane containing di-(2-ethylhexyl)phosphoric acid (D2EHPA) through slug flow in millimeter-diameter glass and polytetrafluoroethylene (PTFE) tubes. The PTFE tube produced a higher initial mass transfer coefficient than the glass tube by increasing internal circulation in the organic phase, and maintained its specific surface area. Slug flow occurred in the PTFE tube when the interfacial tension between the aqueous and organic phases exceeded 50–55 mN/m, which increased the rate of extraction owing to increased circulation in both phases. The addition of tributyl phosphate (TBP) enhanced the extraction efficiency, but did not affect the extraction rate.
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