Abstract
New apparatus to measure liquid–liquid or solid–liquid equilibria by a synthetic method has been built and described. It was used to determine the liquid–liquid equilibrium curves for four binary mixtures of nitromethane+{heptyl methyl ether–CH3OnC7H15, or ethyl hexyl ether–C2H5OnC6H13, or pentyl propyl ether nC3H7OnC5H11, or dibutyl ether nC4H9OnC4H9}. The influence of position of the ethereal group on the solubility curve has been discussed.
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