Abstract
ESCA measurements and effective core potential (ECP) calculations have been performed on the 3d hole states of the I 3 − ion. The ESCA spectra, obtained from liquid solutions show substantial shake-up structure as well as a non-stoichiometric intensity ratio between the 3d lines for the two types of iodine in the I 3 − ion. A mechanism is proposed involving a preferential excitation of shake-up transitions in the ionization of the non-central iodine atoms in the I 3 − ion. The ECP calculations confirm the proposed explanation and predict line energies and intensities in good agreement with the experimental I 3d spectrum.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
