Abstract
The effect of bidispersity on the isotropic-nematic transition is discussed within the framework of Onsager's second-virial theory. The behaviour of bidisperse hard rods beyond the nematic phase is investigated by simulating binary mixtures of hard parallel spherocylinders with different lengths. The behaviour of these mixtures differs markedly, quantitatively as well as qualitatively, from the phase behaviour of the separate monodisperse components. In particular, it is observed that bidispersity favours columnar order over smectic order.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.