Abstract
In iron mixed-valence complex, (n-C3H7)4N[FeIIFeIII(dto)3] (dto = C2O2S2), the linkage isomerisation and charge-transfer between FeII FeIII occur in the precipitation process. We succeeded the suppression of linkage-isomerization and charge-transfer in the formation process of (n-C3H7)4N[FeIIFeIII(dto)3] by the synthesis on low temperature condition and the selection of solvent. Moreover, we have found that the charge transfer occurs in the formation of (n-C4H9)4N[FeIIFeIII(mto)3] (mto = C2O3S) without linkage-isomerization.
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