Lightweight and tough PP/talc composite foam with bimodal nanoporous structure achieved by microcellular injection molding

Abstract

Although polypropylene (PP) foams fabricated by microcellular injection molding (MIM) have been widely studied and globally applied, it is still a big challenge to achieve lightweight products with high mechanical performance. Herein, the MIM method assisted by a fast cooling design was applied to prepare lightweight bimodal nanoporous PP foams with high toughness. A specific mold with a thin cavity was designed to achieve rapid cooling rate during MIM process, and to further accelerate crystallization and refine crystals, which was verified by visualization results, DSC curves, and WAXD patterns. Thus, nanocellular PP foams were prepared, whose high toughness was presented in tensile testing, especially for bimodal cellular foams, more than 327% higher than that of microcellular foams, and up to 53% higher than that of solid. It is owing to the introduced matrix craze, shear yielding, and larger plastic zone by nanocells and the transformed crack propagation direction by microcells. Therefore, this novel toughening method paves a promising prospect for MIM technology to achieve lightweight and tough products for industrial applications.