Abstract

Visible light emission observed in biased comb-type capacitors with a copper (Cu) damascene structure appears to be caused by electroluminescence. Photon emission probably occurs via energy states related to dangling bonds formed at a chemical-mechanical polished (CMP) surface. These energy states also appear to degrade the time-dependent dielectric breakdown (TDDB) characteristics and to increase line-to-line leakage currents. Ammonia (NH3) plasma treatment of a Cu-CMP surface dramatically improved TDDB and decreased the leakage currents. We attribute this to a reduced energy-state density through the termination of dangling bonds by hydrogen generated from the NH3 plasma.

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