Abstract
By-product hydrogen from chlor-alkali processes can help meet the increasing demand for hydrogen fuel in early fuel cell electric vehicle markets (e.g., California) in the U.S. Hydrogen produced from chlor-alkali plants is typically combusted for process heat on site, vented to the atmosphere (i.e., wasted), or sold to the external merchant hydrogen market. Whether it is combusted, vented, or sold as a commodity, relevant information is lacking as to the life-cycle environmental benefits or trade-offs of using by-product hydrogen from chlor-alkali plants. A life-cycle analysis framework was employed to evaluate well-to-gate greenhouse gas (GHG) emissions associated with by-product hydrogen from chlor-alkali processes in comparison with hydrogen from the conventional centralized natural gas steam methane reforming (central SMR) pathway. U.S.-specific, plant-by-plant, and up-to-date chlor-alkali production characteristics were incorporated into the analysis. In addition to the venting and combustion scenarios, to deal with the multi-functionality of the chlor-alkali processes that simultaneously produce chlorine, sodium hydroxide, and hydrogen, two different co-product allocation strategies were adopted—mass allocation and market value allocation. It was estimated that by-product hydrogen production from chlor-alkali processes creates 1.3–9.8 kg CO2e/kg H2 of life-cycle GHG emissions on average, which is 20–90% less than the conventional central SMR pathway. The results vary with co-product treatment scenarios, regional electric grid characteristics, on-site power generation, product prices, and hydrogen yield. Despite the variations in the results, it was concluded that the life-cycle GHG emission reduction benefits of using by-product hydrogen from chlor-alkali processes are robust. With a diverse set of scenario analyses, the study developed a comprehensive and detailed life-cycle GHG emissions inventory of the chlor-alkali by-product hydrogen pathway and quantified sensitivity indices in the context of different assumptions and input parameter values.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.