LiBa1.5[B5O8(OH)3]: A new 1-D metal borate chain constructed from B5O9(OH)36 − cluster units

Han-Qing Wu,Bai-Fei Yang,Huan He,Guo-Yu Yang

doi:10.1016/j.inoche.2013.10.043

LiBa1.5[B5O8(OH)3]: A new 1-D metal borate chain constructed from B5O9(OH)36 − cluster units

Han-Qing Wu, Bai-Fei Yang + Show 2 more

https://doi.org/10.1016/j.inoche.2013.10.043

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Journal: Inorganic Chemistry Communications	Publication Date: Nov 5, 2013
Citations: 5

Affiliation: Beijing Institute of Technology, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences

#Single Crystal X-ray Diffraction #Cluster Units + Show 8 more

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Abstract

A new mixed metal borate LiBa1.5[B5O8(OH)3] (1) has been hydrothermally synthesized and structurally characterized by FT-IR spectroscopy, powder X-ray diffraction, single crystal X-ray diffraction, and thermogravimetric analysis, respectively. 1 crystallizes in the monoclinic system, space group C2/c, a=11.2839(7) Å, b=7.3974(4) Å, c=20.7151(13) Å, β=103.392(6)°, V=1682.10(17) Å3 and Z=8. The structure consists of infinite one-dimensional (1-D) borate chains constructed from B5O9(OH)36− cluster units. These BO chains are further linked by the Ba2+ and Li+ cations to form a 3-D framework.

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