Abstract
Two Crystalline adducts of sodium amide 1 and 2 adopt contrasting binuclear structures, as revealed by X‐ray diffraction. Thus, the bidentate anions are linked to the Na⊕ ions in a terminal manner in 1 but in a bridging manner in 2. Each structure also displays unusual donor‐acceptor coordinations, with PA bridging to Na⊕ in 1, while only two of the three available PMDETA nitrogen centers complex to Na⊕ in 2. equation image
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More From: Angewandte Chemie International Edition in English
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