Leather Solid Waste/Poly(vinyl alcohol)/Polyaniline Aerogel with Mechanical Robustness, Flame Retardancy, and Enhanced Electromagnetic Interference Shielding.

Abstract

Renewable biobased aerogels display a promising potential to fulfill the surging demand in various industrial sectors. However, its inherent low mechanical robustness, flammability, and lack of functionality are still huge obstacles in its practical application. Herein, a novel integrated leather solid waste (LSW)/poly(vinyl alcohol) (PVA)/polyaniline (PANI) aerogel with high mechanical robustness, flame retardancy, and electromagnetic interference (EMI) shielding performance was successfully prepared. Amino carboxyl groups in LSW could be effectively exposed by solid-state shear milling (S3 M) technology to form strong hydrogen-bond interactions with the PVA molecular chains. This led to a change in the compressive strength and the temperature of the initial dimensional change to 15.6 MPa and 112.7 °C at a thickness of 2.5 cm, respectively. Moreover, LSW contains a large number of N elements, which ensures a nitrogen-based flame-retardant mechanism and increase in the limit oxygen index value of LSW/PVA aerogel to 32.0% at a thickness of 2.5 mm. Notably, by the cyclic coating method, a conductive PANI layer could be polymerized on the surface of LSW/PVA aerogel, which led to the construction of a sandwich structure with impressive EMI shielding capability. The EMI shielding effectiveness (SE) reached more than 40 dB, and the specific shielding effectiveness (SSE) reached 73.0 dB cm3 g-1. The inherent dipoles in collagen fibers and the conductive PANI synergistically produced an internal multiple reflection and absorption mechanism. The comprehensive performance of LSW/PVA/PANI aerogel not only demonstrates a new strategy to recycle LSW in a more value-added way but also sheds some more light on the development of biomass aerogels with high-performance, environmentally friendly, and cost-effective properties.