Abstract

Field monitoring combined with laboratory leaching characterization and geochemical speciation modeling were used to identify important geochemical parameters and controlling mechanisms for leaching of oxyanions from coal ash in a disposal site. The site consisted of dry stacked ash on top of a former surface impoundment. Constituents leached from the dry stacked ash served as sources for the soluble fractions of constituents in underlying impoundment ash. Weathering of field ash was evidenced by the identification of calcite and ettringite. Porewater concentrations of As, B, and V in the field pH range (9–11) and liquid-to-solid ratio (L/S) condition (∼0.6 L/kg-dry) were primarily controlled by Ca-bearing precipitates (Ca-arsenate, B-substituted carbonate solid solution, Ca-vanadate, and V-substituted ettringite solid solution). The leachable fraction of Mo as a function of pH was limited by the available content in the solid, with aqueous concentrations of Mo being a function of L/S. Leaching behavior of Cr and Se was sensitive to the redox changes (from suboxic to oxic conditions) during field ash collection and laboratory leaching tests, including oxidative dissolution of insoluble Cr(III)-oxides and conversion of Se(0) in the solid to dissolved Se(IV)/Se(VI). Oxidation resulted in increased Cr concentrations from < 0.00005 (in porewater) to 0.001–0.1 mg/L (in laboratory eluates). The identified geochemical parameters and leaching-controlling mechanisms provide the bases for understanding and estimating the partitioning of oxyanions in other disposal sites with alkaline and suboxic conditions. This case study also provides a typical example of laboratory test results interpretation and field leaching behavior estimation for other studies.

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.