Abstract
The process of combustion in coal fired power plant generates ashes, namely fly ash (FA) and bottom ash (BA). In addition, coal ash generated from coal combustion generally contains heavy metals within their compositions. These metals are toxic to the environment as well as to the human health. Fortunately, treatment methods are available for these ashes and the use of FA and BA in concrete mix is one of the few. As such, this study presents the work in determining the leachability of self-compacting concrete (SCC) incorporated with FA and BA. The ashes were obtained from Kapar Energy Ventures power plant in Kapar, Selangor. SCC mixtures incorporated with 10%, 20% and 30% FA (replacing cement) and BA (replacing sand) respectively was formulated and casted. The samples were then crushed to be extracted using Toxicity Characteristic Leaching Procedure (TCLP) and heavy metals content within the samples were identified accordingly using Atomic Absorption Spectrometry (AAS). From the results, it was found that incorporation up to 30% of the ashes were safe as the leached heavy metals concentration did not exceed the regulatory levels, except for arsenic (As). On the other hand, incorporation of 20% FA and BA each in SCC provided the most economically viable product, with high strength and low leachate concentrations. In conclusion, this study will serve as a reference which suggests that FA and BA are widely applicable in concrete technology and its incorporation in SCC constitutes a potential means of adding value with appropriate mix and design.
Highlights
Fly ash (FA) and bottom ash (BA) are some of the residues produced from the combustion process in an incineration plant
Incorporation up to 30% of fly ash (FA) and BA each or both ashes together in self-compacting concrete (SCC) in this research did not produce a leachate concentration which will serve as a threat to the environment and its surroundings when crushed
In order to determine the characteristics of FA and BA, raw samples of the ashes were obtained and analyzed using X-ray fluorescence (XRF)
Summary
Fly ash (FA) and bottom ash (BA) are some of the residues produced from the combustion process in an incineration plant. FA and BA both contain a variety of hazardous elements such as leachable heavy metals, soluble salts and organic compounds. This must be acknowledged as a concerning threat to the environment as well as its jeopardizing impact on life. The aim of this research was to incorporate the contaminated ashes, FA and BA, into the application of SCC as building materials. A total number of 10 specimens including control SCC with 0% of ashes incorporation were prepared and studied in this research. TCLP was used as a set of instructions to prepare extracted samples of concrete specimens in order for leachate analysis to be done. Fluid portion of the sample was preserved to a pH less than 2.0 and stored in a refrigerator at 5 °C for leachate determination analysis using AAS, which was performed using Perkin Elmer AAnalyst 800
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