Abstract
Vanadium oxides are potential positive electrode materials for aqueous zinc ion batteries (ZIBs) owing to their advantages of high theoretical capacity, low cost, and so on. Developments of methods for preparing binder-free vanadium oxide electrodes on a large scale and further investigation of their Zn2+ storage mechanisms are essential for expanding their uses in large-scale energy storage systems and wearable electronics. In this work, binder-free electrodes with hydrated vanadium oxide (V2O5·nH2O, denoted as VOH)-acetylene black (AB) on carbon cloth (VOH-AB/CC) are fabricated by a simple and scalable method which combined low-temperature hydrothermal treatment with layer-by-layer drop/spray-coating process. The AB can greatly improve the electrical conductivity of VOH, thereby enhancing the electrochemical performance. The as-prepared electrode with 20 wt% of AB (VOH-AB2/CC) delivers a high capacity of 280 mA h g−1 at 1 A/g and a good rate capability of 205 mA h g−1 at 4 A/g, which is better than many of the reported binder-free vanadium base electrodes. Besides, excellent cycling performance with 89 % retention rate after 3000 cycles at 4 A/g is achieved on the VOH-AB2/CC electrode. Furthermore, a storage mechanism of Zn2+/H+/H2O insertion accompanied by the formation of basic zinc salt precipitate during the discharging process is proposed by the aid of ex-situ XRD and XPS techniques. Additionally, the flexible Quasi-Solid-State ZIB constructed using VOH-AB/CC as positive electrode can work well at different bending states and two ZIBs connected in series can lighten a light-emitting diode even under bending state. This work provides a low-cost, time-saving, environmental-friendly and scalable method to fabricate binder-free hydrated vanadium oxide electrodes for flexible aqueous ZIBs.
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