Abstract

We argue that the basic mechanism stabilizing the blue phases is the appearance of double cholesteric twist. The free-energy cost of the disclination lattice that inevitably accompanies double twist becomes small near the clearing point. We use the director picture and the Oseen-Frank equations in a computer calculation of the free energy for three specific models, with ${O}^{5}$, ${O}^{2}$, and ${O}^{8}$ symmetry. Disclinations are treated as having an isotropic core. Comparison of the results of the computation with a number of experimental quantities is given. In a final section, a mean-field theory of disclinations is presented. It is argued there that the biaxiality, which is a characteristic of Landau theories of the blue phase, can be considered as an escape of the core of the disclination, forced by the implicit requirement of analyticity.

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