Abstract
Recent progress in investigations of the reactivity of the CF 3SiMe 3/TASF system, amido- and alkylamidophosphites to different type of electrophiles will be reported. The processes developed make it possible to introduce into organic molecules a range of fluorinated anions of a broad spectrum of nucleophilicity. The possible mechanism of the reactions, and spectral and single crystal X-ray data of the compounds obtained are discussed.
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